In situ preparation of g-C3N4/Bi4O5I2 complex and its elevated photoactivity in Methyl Orange degradation under visible light

A graphite carbon nitride(g-C_3N_4) modified Bi_4O_5I_2 composite was successfully prepared insitu via the thermal treatment of a g-C_3N_4/Bi OI precursor at 400°C for 3 hr.The as-prepared g-C_3N_4/Bi_4O_5I_2 showed high photocatalytic performance in Methyl Orange(MO) degradation under visible light.The best sample presented a degradation rate of 0.164 min~(-1),which is 3.2 and 82 times as high as that of Bi_4O_5I_2 and g-C_3N_4,respectively.The g-C_3N_4/Bi_4O_5I_2 was characterized by X-ray powder diffractometer(XRD),scanning electron microscopy(SEM),transmission electron microscopy(TEM),Raman,X-ray photoelectron spectroscopy(XPS),ultraviolet-visible diffuse reflectance spectra(DRS),electrochemical impedance spectroscopy(EIS) and transient photocurrent response in order to explain the enhanced photoactivity.Results indicated that the decoration with a small amount of g-C_3N_4 influenced the specific surface area only slightly.Nevertheless,the capability for absorbing visible light was improved measurably,which was beneficial to the MO degradation.On top of that,a strong interaction between g-C_3N_4 and Bi_4O_5I_2 was detected.This interplay promoted the formation of a favorable heterojunction structure and thereby enhanced the charge separation.Thus,the g-C_3N_4/Bi_4O_5I_2 composite presented greater charge separation efficiency and much better photocatalytic performance than Bi_4O_5I_2.Additionally,g-C_3N_4/Bi_4O_5I_2 also presented high stability.·O_2~-and holes were verified to be the main reactive species.     

新疆阿尔泰地槽成矿元素分布特征

新疆阿尔泰地槽内成矿元素 ,自北东向南西分为四个带 ,每个带内分布有元素区和矿床 :①阿尔泰山北缘元素带 (阿克萨拉等区 ) ;②阿尔泰山中脊元素带 (冲呼等五个区和可可托海 3号脉稀有金属矿等矿床 ) ;③阿尔泰山南缘元素带 (阿舍勒等四个区和阿舍勒铜矿等矿床 ) ;④额尔齐斯元素带 (喀拉通克等区和喀拉通克铜镍矿等矿床 )。成矿元素区带是寻找新矿床的有利地段     

土地复垦后的验收标准及分级探讨

对应复垦土地复垦后的验收提出了一套分类标准，以便计算土地复垦率，使全国土地复垦工会具有横向对比性。     

Climatic change and urbanization effect in China

Climatic change and urbanization effect in China during the last 39 years were investigated. It is found that a warming of about 0.23℃ for the annual temperature has been noticed from 1951 to 1989. The warmings of about 0.78 ℃ in winter and 0.34 3℃ in spring have been shown. It is also presented that a cooling of about -0.27℃ in summer has been indicated. The bigger cities are warmer than smaller cities in China. The dried trends in the annual precipitation during the last 39 years were presented. The precipitation decreased obviously in summer all over China. The bigger cities were drier than smaller cities.     

Sensitivity experiments and assessment of climatic changes in China induced by greenhouse effect

Climatic changes can be separated into two parts: natural changes -and human activity influenced on climatic changes. The observed data could not only show the effects caused by human activity. Several simulated results as simulated by the GCMs induced by the greenhouse effects in China .have been analysed. It is shown that an obvious warming of about 3-6℃ in winter and 2-5℃ in summer in China as simulated by the GCMs induced by doubling CO2 have been found. There are getting drier or wetter regions in China due to doubled CO2 as simulated by most of models. Comparing the simulated results with the observed data in China, some simulated results are able to be believed. The GCMs should be improved, especially in the regional areas.     

序批式反应器的水力停留时间的理论探讨

根据液龄分布函数是二元函数的观点．推导出了当进、出水流量是时间的函数时，反应器的水力停留时间的通用积分式和离散式；然后得出了序批式反应器(SBR）的水力停留时间(HRT)具体表达式，并分析了用现有方法计算其水力停留时间所产生的误差．结果表明，最大相对误差rmax仅与充水比λ有关．且呈正相关关系．取典型值λ=0．4时，rmax高达25％。     

取代苯甲酸在天然河流中的生物降解及其定量结构--生物降解性相关研究

以天然河流水作为微生物源 ,采用碘量法测定了 2 0种苯甲酸类化合物的 5日生化需氧量 ,并以其占理论需氧量的百分数作为表征生物降解性的参数 ,得出各类取代苯甲酸类化合物的生物降解能力为 :羟基 >氨基 >羧基 >甲氧基 >氯基 >硝基 ;对于同一种取代基 ,对位取代基化合物生物降解能力最大 ,而邻位、间位取代基化合物生物降解能力大体相同。计算了苯甲酸类化合物的分子连接性指数 ,并以 5日生化需氧量占理论需氧量的百分数为参数建立了 QSBR模型。分析结果表明 ,分子连接性指数5Xvpc、5Xp- 5Xvp 能较好地反映取代苯甲酸的生物降解性     

Water solubility enhancements of PAHs by sodium castor oil sulfonate microemulsions

Water solubility enhancements of naphthalene( Naph), phenantherene(Phen) and pyrene(Py) in sodium castor oil sulfonate(SCOS) microemulsions were evaluated. The apparent solubilities of PAHs are linearly propertional to the concentrations of SCOS microemulsion, and the enhancement extent by SCOS solutions is greater than that by ordinary surfactants on the basis of weight solubilization ratio(WSR). ThelogKcm values of Naph, Phen, and Py are 3.13, 4.44 and 5.01 respectively, which are about the same as the logKow values. At 5000 mg/L of SCOS conccentration, the apparent solubilities are 8.80, 121, and 674 times as the intrinsic solubilities for Naph, Phen, and Py. The effects of inorganic ions and temperature on the solubilization of solutes are also investigated. The solubilization is improved with a moderate addition of Ca^2 , Na^ , NH4^ and the mixture of Na^ , K^ , Ca^2 , Mg^2 and NH4^ . WSR values are enhanced by 22.0% for Naph,23.4% for Phen, and 24.6% for Py with temperature increasing by 5~C. The results indicated that SCOS microemulsions improve the performance of the surfactant-enhanced remediation(SER) of soil, by increasing solubilities of organic pollutants and reducing the level of surfactant pollution and remediation expenses.     

Sustainable development pattern and the strategy in the three Gorges Reservoir Areas

The development pattern,development situation,and existing problems of land exploitation in Zigui County,Three Gorges Reservoir Areas of China were presented.The sustainable development mode and its strategy in the Three Gorges Reservoir Areas was also discussed.A sustainable development framework for low mountain regions,middle mountain regions and high mountain regions was developed,and management countermeasures for structural optimization of complex ecosystems were advanced.     

佳木斯台形变观测对东北地区几次浅震“场兆”异常的探讨

大地震在主破裂前往往行成地壳变形,高应力作用下进入峰值后的变形阶段,反映到地倾斜观测日均值曲线上,表现为固体潮形变趋势异常,这些异常能否指示远距离的地震,近年来不少研究者发现,远场前兆往往出现在对应力、应变变化反应灵敏的特殊构造部位。佳木斯台可能处于这种特殊的构造部位,对东北地区浅源地震短期前兆异常“场兆”的趋势性变化具有一定的意义。